Low thermal conductivity of SrTiO3−LaTiO3 and SrTiO3−SrNbO3 thermoelectric oxide solid solutions

Yuqiao Zhang*, Hai Jun Cho, Kenyu Sugo, Masashi Mikami, Sungmin Woo, Myung Chul Jung, Yao Hua Zhuang, Bin Feng, Yu Miin Sheu, Woosuck Shin, Woo Seok Choi, Myung Joon Han, Yuichi Ikuhara, Hiromichi Ohta

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review


Electron-doped SrTiO3 has been attracting attention as oxide thermoelectric materials, which can convert wasted heat into electricity. The power factor of the electron-doped SrTiO3, including SrTiO3-LaTiO3 and SrTiO3-SrNbO3 solid solutions, has been clarified. However, their thermal conductivity (κ) has not been clearly identified thus far. Only a high κ (>12 W m−1 K−1) has been assumed from the electron contribution based on Wiedemann–Franz law. Here, we show that the κ of the electron-doped SrTiO3 is lower than the assumed κ, and its highest ZT exceeded 0.1 at room temperature. The κ slightly decreased with the carrier concentration (n) when n is below 4 × 1021 cm−3. In the case of SrTiO3-SrNbO3 solid solutions, an upturn in κ was observed when n exceeds 4 × 1021 cm−3 due to the contribution of conduction electron to the κ. On the other hand, κ decreased in the case of SrTiO3-LaTiO3 solid solutions probably due to the lattice distortion, which scatters both electrons and phonons. The highest ZT was 0.11 around n = 1 × 1021 cm−3. These findings would be useful for the future design of electron-doped SrTiO3-based thermoelectric materials.

Original languageEnglish
JournalJournal of the American Ceramic Society
StateAccepted/In press - 2021


  • lattice distortion
  • polaron
  • strontium titanate
  • thermal conductivity
  • thermoelectrics

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