Abstract
Lithium dienolates of α,β-unsaturated acylsilanes can be conveniently obtained by the reaction of (1-silylallyl)lithiums with carbon monoxide at ambient temperature. This reaction represents a rare example of α-selective C-C bond formation for an ambident 1-silylallyl anion, which may be rationalized by assuming an equilibration process.
| Original language | English |
|---|---|
| Pages (from-to) | 5459-5461 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 15 |
| Issue number | 26 |
| DOIs | |
| State | Published - 24 Dec 1996 |
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Ryu, I., Yamamoto, H., Sonoda, N., & Murai, S. (1996). Lithium dienolate generation by α-regioselective reaction of (1-silylallyl)lithiums with carbon monoxide. Organometallics, 15(26), 5459-5461. https://doi.org/10.1021/om9608014