Abstract
Lithium dienolates of α,β-unsaturated acylsilanes can be conveniently obtained by the reaction of (1-silylallyl)lithiums with carbon monoxide at ambient temperature. This reaction represents a rare example of α-selective C-C bond formation for an ambident 1-silylallyl anion, which may be rationalized by assuming an equilibration process.
Original language | English |
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Pages (from-to) | 5459-5461 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 15 |
Issue number | 26 |
DOIs | |
State | Published - 24 Dec 1996 |