Lithium dienolate generation by α-regioselective reaction of (1-silylallyl)lithiums with carbon monoxide

Ilhyong Ryu, Haruhiko Yamamoto, Noboru Sonoda, Shinji Murai*

*Corresponding author for this work

Research output: Contribution to journalArticle

24 Scopus citations

Abstract

Lithium dienolates of α,β-unsaturated acylsilanes can be conveniently obtained by the reaction of (1-silylallyl)lithiums with carbon monoxide at ambient temperature. This reaction represents a rare example of α-selective C-C bond formation for an ambident 1-silylallyl anion, which may be rationalized by assuming an equilibration process.

Original languageEnglish
Pages (from-to)5459-5461
Number of pages3
JournalOrganometallics
Volume15
Issue number26
DOIs
StatePublished - 24 Dec 1996

Fingerprint Dive into the research topics of 'Lithium dienolate generation by α-regioselective reaction of (1-silylallyl)lithiums with carbon monoxide'. Together they form a unique fingerprint.

  • Cite this