Linear, mixed-valent homocatenated tri-tin complexes featuring Sn-Sn bonds

Wei Chieh Chang, Ankit Raj, Ankit Raj, Hirotsugu Hiramatsu, Hirotsugu Hiramatsu, Hirotsugu Hiramatsu, Han Jung Li, Micah S. Ziegler, Yichen Lin, Shengcih Huang, Hsueh Ju Liu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

A series of tri-tin complexes (LPhSn)3X with triple-decker structures (LPh = 2,5-di(o-pyridyl)-3,4-diphenylpyrrolate; X = Cl, AlCl4, OTf, and PF6) was synthesized by reducing LPhSnCl with LiBsBu3H and subsequent reactions. Structural characterization of (LPhSn)3Cl revealed a Sn-Sn-Sn core, and DFT calculations suggest that its HOMO is primarily σ-bonding along the tri-tin framework. (LPhSn)3Cl reacts with W(CO)5THF to afford (LPhSn)2(W(CO)5)2 and LPhSnCl, implying that (LPhSn)3Cl may exhibit dynamic behavior in solution.

Original languageEnglish
Pages (from-to)6786-6789
Number of pages4
JournalChemical Communications
Volume56
Issue number50
DOIs
StatePublished - 25 Jun 2020

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