Laser-induced fluorescence excitation spectrum of CCl2 cooled in a supersonic free jet

Qingzheng Lu, Yang Chen, Dongqing Wang, Yunwu Zhang, Shuqin Yu, Congxiang Chen, Mitsuo Koshi, Hiroyuki Matsui, Seiichiro Koda, Xingxiao Ma*

*Corresponding author for this work

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Abstract

Laser-induced fluorescence (LIF) excitation spectrum for gas-phase dichlorocarbene (CCl2) cooled in a supersonic free jet has been observed in the wavelength range of 497-517 nm. The K-structure was clearly resolved. About 80 subbands were assigned to (v1, v2 0)←(0, 0, 0) vibronic transitions. The vibrational frequencies of ν′1=643.5 cm-1, ν′2=308,0 cm-1 and their anharmonic constants were obtained. Furthermore, the rotational data A′-B′=3.67 cm-1, A″-B″=1.80 cm-1 were deduced from the spectral analysis.

Original languageEnglish
Pages (from-to)517-522
Number of pages6
JournalChemical Physics Letters
Volume178
Issue number5-6
DOIs
StatePublished - 5 Apr 1991

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    Lu, Q., Chen, Y., Wang, D., Zhang, Y., Yu, S., Chen, C., Koshi, M., Matsui, H., Koda, S., & Ma, X. (1991). Laser-induced fluorescence excitation spectrum of CCl2 cooled in a supersonic free jet. Chemical Physics Letters, 178(5-6), 517-522. https://doi.org/10.1016/0009-2614(91)87012-Z