Laser-controlled assembling of repulsive unimolecular micelles in aqueous solution

Jun Ichi Hotta, Keiji Sasaki*, Hiroshi Masuhara, Yotaro Morishima

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

Laser manipulation techniques were applied to the control of molecular assembling in D2O. An amphiphilic random copolymer, which has hydrophilic and hydrophobic segments in a single chain and forms a monopolymer micelle through self-organization, is demonstrated to receive photon pressure of a focused near-infrared laser beam. Upon prolonged irradiation with the beam, a single microparticle is formed at a focal point, and it dissolves very quickly after switching off the laser beam. The behavior indicates that electrostatic repulsion between micelles is overcome by photon pressure. The assembling processes were examined as a function of irradiation time and polymer concentration and are discussed.

Original languageEnglish
JournalJournal of Physical Chemistry B
Volume102
Issue number40
DOIs
StatePublished - 1 Oct 1998

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