Kinetics of the C6H5 + NO association reaction

T. Yu*, Ming-Chang Lin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

58 Scopus citations

Abstract

The rate constants for the C6H5 + NO → C6H5NO reaction have been measured with the cavity-ring-down method between 298 and 500 K to be k = 10-11.35±0.06 exp[(+433 ± 111)/T] cm3/s. The effect of pressure was examined at 388 K by sextupling of the total pressure from 20 to 120 Torr, with no significant increase in the measured rate constants within the scatter of the data. This is consistent with the k/k ratio predicted for 388 K using the known literature value of k for the unimolecular decomposition of nitrosobenzene. Our result for C6H5 + NO compares reasonably with the values for other R· + NO association reactions.

Original languageEnglish
Pages (from-to)2105-2109
Number of pages5
JournalJournal of physical chemistry
Volume98
Issue number8
DOIs
StatePublished - 1 Jan 1994

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