Kinetics of CH radical reactions with selected molecules at room temperature

J. E. Butler*, J. W. Fleming, L. P. Goss, Ming-Chang Lin

*Corresponding author for this work

Research output: Contribution to journalArticle

145 Scopus citations

Abstract

The rate constants for reactions of the CH radical with selected molecules relevant to hydrocarbon combustion systems have been measured at room temperature. The CH radical was generated by multiphoton dissociation of CHBr3 at 193 nm and monitored by laser induced fluorescence using a pulsed tunable dye laser operating in the 420-440 nm region. The mechanisms of these reactions have been discussed in terms of observed rates and other thermochemical data.

Original languageEnglish
Pages (from-to)355-365
Number of pages11
JournalChemical Physics
Volume56
Issue number3
DOIs
StatePublished - 15 Apr 1981

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