Kinetics for the recombination of phenyl radicals

J. Park, Ming-Chang Lin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

The rate constant for the C6H5 + C6H5 recombination reaction has been determined in the temperature range 300-500 K using a laser photolysis/mass spectrometric technique. The result is represented by k1 = (1.39 ± 0.11) × 1013e-(56±36)/T cm3/(mol s). In addition, the rate constant for the C6H5 + C6H5NO association reaction was found to be k4 = (4.90 ± 0.19) × 1012e(34±16)/T cm3/(mol s) by the mass balance of the initial concentration of C6H5 radicals. Using the result of k1, previous kinetic data for C6H5 reactions determined by the conventional relative rate method were reanalyzed.

Original languageEnglish
Pages (from-to)14-18
Number of pages5
JournalJournal of Physical Chemistry A
Volume101
Issue number1
DOIs
StatePublished - 2 Jan 1997

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