Isomers of HSCO: IR absorption spectra of t-HSCO in solid Ar

Wen Jui Lo*, Hui Fen Chen, Yu Jong Wu, Yuan-Pern Lee

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The possible isomers of trans-HSCO were studied using infrared spectroscopy. It was formed after the irradiation of an argon matrix sample containing H2S and carbon monoxide (CO) (or OCS) with an ArF excimer laser at 193 nm. Typically 600 scans with resolution of 0.5 cm-1 were recorded at each stage of the experiment. The results show that trans-HSCO have energy smaller than that of isomers c-HSCO, HC(O)S and c-HOCS.

Original languageEnglish
Pages (from-to)5717-5722
Number of pages6
JournalJournal of Chemical Physics
Volume120
Issue number12
DOIs
StatePublished - 22 Mar 2004

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