Isomers of HSCO: IR absorption spectra of t-HSCO in solid Ar

Wen Jui Lo; Hui Fen Chen; Yu Jong Wu; Yuan-Pern Lee

doi:10.1063/1.1648634

Isomers of HSCO: IR absorption spectra of t-HSCO in solid Ar

Wen Jui Lo^*, Hui Fen Chen, Yu Jong Wu, Yuan-Pern Lee

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The possible isomers of trans-HSCO were studied using infrared spectroscopy. It was formed after the irradiation of an argon matrix sample containing H₂S and carbon monoxide (CO) (or OCS) with an ArF excimer laser at 193 nm. Typically 600 scans with resolution of 0.5 cm^-1 were recorded at each stage of the experiment. The results show that trans-HSCO have energy smaller than that of isomers c-HSCO, HC(O)S and c-HOCS.

Original language	English
Pages (from-to)	5717-5722
Number of pages	6
Journal	Journal of Chemical Physics
Volume	120
Issue number	12
DOIs	https://doi.org/10.1063/1.1648634
State	Published - 22 Mar 2004

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title = "Isomers of HSCO: IR absorption spectra of t-HSCO in solid Ar",

abstract = "The possible isomers of trans-HSCO were studied using infrared spectroscopy. It was formed after the irradiation of an argon matrix sample containing H2S and carbon monoxide (CO) (or OCS) with an ArF excimer laser at 193 nm. Typically 600 scans with resolution of 0.5 cm-1 were recorded at each stage of the experiment. The results show that trans-HSCO have energy smaller than that of isomers c-HSCO, HC(O)S and c-HOCS.",

author = "Lo, {Wen Jui} and Chen, {Hui Fen} and Wu, {Yu Jong} and Yuan-Pern Lee",

year = "2004",

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AU - Lo, Wen Jui

AU - Chen, Hui Fen

AU - Wu, Yu Jong

AU - Lee, Yuan-Pern

PY - 2004/3/22

Y1 - 2004/3/22

N2 - The possible isomers of trans-HSCO were studied using infrared spectroscopy. It was formed after the irradiation of an argon matrix sample containing H2S and carbon monoxide (CO) (or OCS) with an ArF excimer laser at 193 nm. Typically 600 scans with resolution of 0.5 cm-1 were recorded at each stage of the experiment. The results show that trans-HSCO have energy smaller than that of isomers c-HSCO, HC(O)S and c-HOCS.

AB - The possible isomers of trans-HSCO were studied using infrared spectroscopy. It was formed after the irradiation of an argon matrix sample containing H2S and carbon monoxide (CO) (or OCS) with an ArF excimer laser at 193 nm. Typically 600 scans with resolution of 0.5 cm-1 were recorded at each stage of the experiment. The results show that trans-HSCO have energy smaller than that of isomers c-HSCO, HC(O)S and c-HOCS.

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