Isomerization of oxygen-substituted cyclopropanes by metal catalysis

Takashi Sugimura*, Ilhyong Ryu

*Corresponding author for this work

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

Highly regio- and stereospecific isomerization reactions of siloxy- and alkoxycyclopropanes were effected under mild reaction conditions by a variety of metal-catalyzed systems using such as Zn(II), Pt(II), Rh(I), and Ni(0). It is noteworthy that the conversion of siloxycyclopropanes to allyl silyl ethers was established by the use of either zinc iodide or Zeise's dimer. The scope, limitations, and mechanisms of isomerization of siloxy- and alkoxy-substituted cyclopropanes are discussed.

Original languageEnglish
Pages (from-to)1100-1107
Number of pages8
JournalYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
Volume58
Issue number11
DOIs
StatePublished - 1 Jan 2000

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