Intensities of line features in vibration-rotational bands 2-0 to 6-0 of 14N16O X2Πr and experimental evaluation of a radial function for electric dipolar moment

Yuan-Pern Lee; Swee Lan Cheah; J. F. Ogilvie

doi:10.1016/j.infrared.2005.01.002

Intensities of line features in vibration-rotational bands 2-0 to 6-0 of 14N16O X2Πr and experimental evaluation of a radial function for electric dipolar moment

Yuan-Pern Lee, Swee Lan Cheah, J. F. Ogilvie^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

We measured the strengths of individual line-like features, representing unresolved Λ doublets, in vibration-rotational bands 2-0 to 6-0 of ¹⁴N¹⁶O within each substate of electronic ground state X²Π_1/2,3/2 in mid and near infrared regions. Analyses of these data to derive values of matrix elements for vibrational transitions enabled production of a radial function for electric dipolar moment, containing seven parameters, that satisfactorily reproduces the intensities of about 700 such features for vibrational states up to ν = 6.

Original language	English
Pages (from-to)	227-239
Number of pages	13
Journal	Infrared Physics and Technology
Volume	47
Issue number	3
DOIs	https://doi.org/10.1016/j.infrared.2005.01.002
State	Published - 1 Jan 2006

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abstract = "We measured the strengths of individual line-like features, representing unresolved Λ doublets, in vibration-rotational bands 2-0 to 6-0 of 14N16O within each substate of electronic ground state X2Π1/2,3/2 in mid and near infrared regions. Analyses of these data to derive values of matrix elements for vibrational transitions enabled production of a radial function for electric dipolar moment, containing seven parameters, that satisfactorily reproduces the intensities of about 700 such features for vibrational states up to ν = 6.",

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AU - Lee, Yuan-Pern

AU - Cheah, Swee Lan

AU - Ogilvie, J. F.

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Y1 - 2006/1/1

N2 - We measured the strengths of individual line-like features, representing unresolved Λ doublets, in vibration-rotational bands 2-0 to 6-0 of 14N16O within each substate of electronic ground state X2Π1/2,3/2 in mid and near infrared regions. Analyses of these data to derive values of matrix elements for vibrational transitions enabled production of a radial function for electric dipolar moment, containing seven parameters, that satisfactorily reproduces the intensities of about 700 such features for vibrational states up to ν = 6.

AB - We measured the strengths of individual line-like features, representing unresolved Λ doublets, in vibration-rotational bands 2-0 to 6-0 of 14N16O within each substate of electronic ground state X2Π1/2,3/2 in mid and near infrared regions. Analyses of these data to derive values of matrix elements for vibrational transitions enabled production of a radial function for electric dipolar moment, containing seven parameters, that satisfactorily reproduces the intensities of about 700 such features for vibrational states up to ν = 6.

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DO - 10.1016/j.infrared.2005.01.002

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