Hydroalkylation of Alkenes Using Alkyl Iodides and Hantzsch Ester under Palladium/Light System

Shuhei Sumino, Ilhyong Ryu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

The hydroalkylation of alkenes using alkyl iodides with Hantzsch ester as a hydrogen source occurred smoothly under a Pd/light system, in a novel, tin-free Giese reaction. A chemoselective reaction at C(sp3)-I in the presence of a C(sp2)-X (X = Br or I) bond was attained, which allowed for the stepwise functionalization of two types of C-X bonds in a one-pot procedure.

Original languageEnglish
Pages (from-to)52-55
Number of pages4
JournalOrganic Letters
Volume18
Issue number1
DOIs
StatePublished - 4 Jan 2016

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