Gas-phase generation of highly reactive hexatriyne-bridged [6 n]paracyclophynes

Rui Umeda, Takayoshi Morinaka, Motohiro Sonoda, Tobe Yoshito*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

[6n]Paracyclophenediynes 2a-d (n = 3-6) having [4.3.2]-propellatriene units were prepared as precursors of the corresponding [6n]paracyclophynes. Laser irradiation of 2a-d produced the negative ions of [6n]paracyclophynes 1a-d (n = 3-6) by extrusion of the indan fragments, which were detected by time-of-flight mass spectrometry.

Original languageEnglish
Pages (from-to)6133-6136
Number of pages4
JournalJournal of Organic Chemistry
Volume70
Issue number15
DOIs
StatePublished - 22 Jul 2005

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