Formation of mononuclear nitrido complexes of chromium(VI) and molybdenum(VI); syntheses and X-ray crystal structures of N≡Cr(OBut)3 and N≡Mo(OSiMe3)3(py)

Hsin-Tien Chiu*, Yi Pin Chen, Shiow Huey Chuang, Jiung Shung Jen, Gene Hsiang Lee, Shie Ming Peng

*Corresponding author for this work

Research output: Contribution to journalArticle

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Abstract

Mononuclear nitrido complexes of Cr and Mo, N≡Cr(OBut)3 and N≡Mo(OSiMe3)3(py), are synthesized; the chromium complex has an idealized C3v, symmetry while the molybdenum complex has a distorted square-pyramidal geometry with the nitrido ligand at apical position; the N-Cr distance is 1.538(5) Å while the average N-Mo distance is 1.627 Å.

Original languageEnglish
Pages (from-to)139-140
Number of pages2
JournalChemical Communications
Issue number2
DOIs
StatePublished - 1 Jan 1996

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