We will focus on a model with a scalar-vector coupling and a scalar Kalb-Ramond coupling. The Kalb-Ramond two-form is known to be equivalent to a U1 gauge one-form in five dimensions. The model with both scalar-vector and scalar Kalb-Ramond interactions is hence effectively equivalent to an action with two independent vector fields. As a result, a new set of spherically symmetric black hole solutions will be presented for the scalar-vector Kalb-Ramond theory in five dimensions. We will show that the presence of the scalar fields and gauge fields affect the black hole structure in a nontrivial manner. Related implications will also be discussed in this paper.