Electrochemical reduction of CO2 by Cu2O-catalyzed carbon clothes

Tin Yu Chang, Ru Meng Liang, Pu-Wei Wu*, Jing Yu Chen, Yu Chi Hsieh

*Corresponding author for this work

Research output: Contribution to journalArticle

67 Scopus citations

Abstract

Cu2O cubes with average edge lengths of 640 nm were prepared by a chemical reduction approach. The as-synthesized Cu2O particles were deposited on carbon clothes for electrochemical characterizations in cyclic voltammetry (CV) and potentiostatic measurements. In 0.5 M NaOH electrolytes saturated with N2 or CO2, both the Cu2O and carbon clothes were stable at the potential range of 0 to - 1.7 V. Comparisons in the current responses from the CV and potentiostatic measurements suggested the Cu2O with notable catalytic abilities for the CO2 reduction. The mass activity was estimated at 0.94 mA/mg. Chemical analysis from gas chromatography confirmed the methanol to be the predominant product.

Original languageEnglish
Pages (from-to)1001-1003
Number of pages3
JournalMaterials Letters
Volume63
Issue number12
DOIs
StatePublished - 15 May 2009

Keywords

  • Alkaline electrolyte
  • CO sequestration
  • CuO
  • Electrochemical reduction

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