Dynamics of reactions of O(3P) atoms with 1-alkynes as studied by a CO laser resonance absorption technique

W. M. Shaub*, T. L. Burks, Ming-Chang Lin

*Corresponding author for this work

Research output: Contribution to journalArticle

10 Scopus citations

Abstract

We have studied the reactions of O(3P) atoms with alkynes in the series acetylene through 1-hexyne at room temperature via the CO laser resonance absorption technique. Observed vibrational population distributions of the CO product were found to be consistent with the general mechanism: {A figure is presented} Based on the measured CO′ product yields, the rate constants or O(3P) + 1-pentyne and 1-hexyne have been evaluated.

Original languageEnglish
Pages (from-to)455-460
Number of pages6
JournalChemical Physics
Volume45
Issue number3
DOIs
StatePublished - 1 Feb 1980

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