Controlling magnetoelectric coupling by nanoscale phase transformation in strain engineered bismuth ferrite

Y. Y. Liu, R. K. Vasudevan, K. Pan, S. H. Xie, W. I. Liang, A. Kumar, S. Jesse, Y. C. Chen, Ying-hao Chu, V. Nagarajan, S. V. Kalinin, J. Y. Li*

*Corresponding author for this work

Research output: Contribution to journalArticle

26 Scopus citations

Abstract

The magnetoelectric coupling in multiferroic materials is promising for a wide range of applications, yet manipulating magnetic ordering by electric field proves elusive to obtain and difficult to control. In this paper, we explore the prospect of controlling magnetic ordering in misfit strained bismuth ferrite (BiFeO 3, BFO) films, combining theoretical analysis, numerical simulations, and experimental characterizations. Electric field induced transformation from a tetragonal phase to a distorted rhombohedral one in strain engineered BFO films has been identified by thermodynamic analysis, and realized by scanning probe microscopy (SPM) experiment. By breaking the rotational symmetry of a tip-induced electric field as suggested by phase field simulation, the morphology of distorted rhombohedral variants has been delicately controlled and regulated. Such capabilities enable nanoscale control of magnetoelectric coupling in strain engineered BFO films that is difficult to achieve otherwise, as demonstrated by phase field simulations.

Original languageEnglish
Pages (from-to)3175-3183
Number of pages9
JournalNanoscale
Volume4
Issue number10
DOIs
StatePublished - 21 May 2012

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    Liu, Y. Y., Vasudevan, R. K., Pan, K., Xie, S. H., Liang, W. I., Kumar, A., Jesse, S., Chen, Y. C., Chu, Y., Nagarajan, V., Kalinin, S. V., & Li, J. Y. (2012). Controlling magnetoelectric coupling by nanoscale phase transformation in strain engineered bismuth ferrite. Nanoscale, 4(10), 3175-3183. https://doi.org/10.1039/c2nr00039c