Colorimetric sensing of Cu(ii): Cu(ii) induced deprotonation of an amide responsible for color changes

Shu-Pao Wu*, Kun Ju Du, Yi Ming Sung

*Corresponding author for this work

Research output: Contribution to journalArticle

69 Scopus citations

Abstract

9,10-Anthraquinone-based chemosensor 1 indicates the presence of Cu(ii) ions among other transition metal ions with high selectivity by a color change from yellow to dark red. Chemosensor 2 shows binding toward Cu(ii), Ni(ii) and Co(ii) with color changes from yellow to dark red, red and pale green, respectively. Especially, Co(ii) binding with chemosensor 2 causes significantly green fluorescence. On addition of Cu(ii), 1 and 2 exhibit 76 and 80 nm red shifts in absorption wavelength (pH 7.0). The effect on pH by the formation of these 1-Cu(ii) and 2-Cu(ii) complexes was determined by UV-vis spectroscopic pH titration. In the pH range of 6-7.5, a maximum absorption was observed at 473 nm and exhibited the formation of deprotonated 1-Cu(ii) and 2-Cu(ii) complexes.

Original languageEnglish
Pages (from-to)4363-4368
Number of pages6
JournalDalton Transactions
Volume39
Issue number18
DOIs
StatePublished - 3 May 2010

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