Chemical lasers produced from O(1D) atom reactions. III. HCl elimination lasers from the O(1D) + CHnCl4-n (n = 1, 2, and 3) reactions

Ming-Chang Lin*

*Corresponding author for this work

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

Chemical HCl laser emissions were observed in the four-centered unimolecular elimination of HCl from vibrationally excited Cl3COH, Cl2HCOH, and ClH2COH molecules in an optical cavity. The vibrationally excited methanol molecule, which possesses at least 130 kcal/mol of internal energy, was generated by insertion of an O(1D) atom into a C-H bond of a chloromethane molecule. The O(1D) atom was produced from the flash-photolytic decomposition of O3. The vibration-rotation transitions of the laser emission were identified, and the initial populations ratios of the highest gain transitions have been estimated.

Original languageEnglish
Pages (from-to)811-813
Number of pages3
JournalThe Journal of Physical Chemistry
Volume76
Issue number6
DOIs
StatePublished - 1 Dec 1972

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