Cascade radical reactions catalyzed by a Pd/light system: Cyclizative multiple carbonylation of 4-alkenyl iodides

Ilhyong Ryu*, Sergio Kreimerman, Fumikazu Araki, Satoshi Nishitani, Yoji Oderaotoshi, Satoshi Minakata, Mitsuo Komatsu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

89 Scopus citations

Abstract

Cascade reactions of 4-alkenyl iodides, involving a carbonylation-cyclization-carbonylation sequence, were accomplished by a hν/Pd system. The stereochemical outcomes suggest that radical carbonylation and subsequent acyl radical cyclization may be involved in this reaction.

Original languageEnglish
Pages (from-to)3812-3813
Number of pages2
JournalJournal of the American Chemical Society
Volume124
Issue number15
DOIs
StatePublished - 17 Apr 2002

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