Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis

Alex Cartier, Etienne Levernier, Vincent Corcé, Takahide Fukuyama*, Anne Lise Dhimane, Cyril Ollivier, Ilhyong Ryu, Louis Fensterbank

*Corresponding author for this work

Research output: Contribution to journalArticle

23 Scopus citations

Abstract

Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.

Original languageEnglish
Pages (from-to)1789-1793
Number of pages5
JournalAngewandte Chemie - International Edition
Volume58
Issue number6
DOIs
StatePublished - 4 Feb 2019

Keywords

  • carbonylation
  • photocatalysis
  • radicals
  • silicates
  • three-component reactions

Fingerprint Dive into the research topics of 'Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis'. Together they form a unique fingerprint.

  • Cite this

    Cartier, A., Levernier, E., Corcé, V., Fukuyama, T., Dhimane, A. L., Ollivier, C., Ryu, I., & Fensterbank, L. (2019). Carbonylation of Alkyl Radicals Derived from Organosilicates through Visible-Light Photoredox Catalysis. Angewandte Chemie - International Edition, 58(6), 1789-1793. https://doi.org/10.1002/anie.201811858