Area-selective passivation of sp2 carbon surfaces by supramolecular self-assembly

Zhi Li, Hans Van Gorp, Peter Walke, Thanh Hai Phan, Yasuhiko Fujita, John Greenwood*, Oleksandr Ivasenko, Kazukuni Tahara, Tobe Yoshito, Hiroshi Uji-I, Stijn F.L. Mertens, Steven De Feyter

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

8 Scopus citations


Altering the chemical reactivity of graphene can offer new opportunities for various applications. Here, we report that monolayers of densely packed n-pentacontane significantly reduce the covalent grafting of aryl radicals to graphitic surfaces. The effect is highly local in nature and on fully covered substrates grafting can occur only at monolayer imperfections such as interdomain borders and vacancy defects. Grafting partially covered substrates primarily results in the covalent modification of uncoated areas.

Original languageEnglish
Pages (from-to)5188-5193
Number of pages6
Issue number16
StatePublished - 28 Apr 2017

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