Application of m-CNTs/NaClO4/Ppy to a fast response, room working temperature ethanol sensor

Ren Jang Wu*, Yu Ching Huang, Ming Ru Yu, Tzu Hsuan Lin, Shih-Lin Hung

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

49 Scopus citations

Abstract

A new blended material, m-CNTs/NaClO4/Ppy, was developed as a gas sensor to detect ethanol concentrations at room temperature. The sensing material polypyrrole (Ppy) was synthesized in situ by UV-photo-polymerization. The multiwall carbon nanotubes (m-CNTs) added enhanced the short-term repeatability of the Ppy-sensing material. The relative resistance variation (Rethanol/Rair) of m-CNTs/NaClO4/Ppy was 1.193 when exposed to ethanol of 30,000 ppm. The sensor response and recovery times (both 20 s) were very short to this concentration. An unstable baseline of the sensor was explained by theoretical calculation of molecular dynamics made for ethanol adsorption on polypyrrole, which revealed formation of a new bond, N-H⋯O. Adsorption energy decreased with increasing the number of ethanol molecules adsorbed and was 0.8 kcal/mol at eight adsorbed molecules. Sensor responses of three different Ppy samples were measured to ethanol concentrations of 18,000-40,000 ppm.

Original languageEnglish
Pages (from-to)213-218
Number of pages6
JournalSensors and Actuators, B: Chemical
Volume134
Issue number1
DOIs
StatePublished - 28 Aug 2008

Keywords

  • Ethanol sensor
  • Multiwall carbon nanotubes (m-CNTs)
  • Polypyrrole
  • UV-photo polymerization

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