Annulation of benzamides with [60]fullerene through palladium(II)-catalyzed C-H bond activation

Shih-Ching Chuang*, Venkatachalam Rajeshkumar, Chun An Cheng, Jie Cheng Deng, Guan Wu Wang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

Palladium-catalyzed heteroannulation of N-substituted benzamides with [60]fullerene, which proceeds through direct sp2 C-H bond activation to form 7-membered ring pallada-intermediate with C60, led to formation of [60]fulleroisoquinolinones in moderate to good yields (8- 64% based on recovered C60). A plausible reaction pathway is proposed.

Original languageEnglish
Pages (from-to)1599-1604
Number of pages6
JournalJournal of Organic Chemistry
Volume76
Issue number6
DOIs
StatePublished - 18 Mar 2011

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