An organic hole transport layer enhances the performance of colloidal PbSe quantum dot photovoltaic devices

Chih Yin Kuo*, Ming Shin Su, Yu Chien Hsu, Hui Ni Lin, Kung-Hwa Wei

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

28 Scopus citations

Abstract

A thin poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) hole transport layer enhances the AM1.5 power conversion efficiency of a PbSe quantum dot (QD)-containing photovoltaic device to 2.4%, from 1.5% for a standard PbSe QD device, a relative increase of 60%. Synchrotron X-ray reflectivity measurements reveal that the roughness of the interfaces between the various layers decreases dramatically in the presence of the PEDOT:PSS layer. In addition, the device life time under continuous simulated AM1.5 irradiation (100 mW cm-2), measured in terms of the time required to reach 80% of the normalized efficiency, for the PbSe QD device incorporating the PEDOT:PSS hole transport layer is six times longer than that of the standard PbSe QD device.

Original languageEnglish
Pages (from-to)3555-3560
Number of pages6
JournalAdvanced Functional Materials
Volume20
Issue number20
DOIs
StatePublished - 22 Oct 2010

Keywords

  • hole transport layers
  • PEDOT:PSS
  • photovoltaic devices
  • quantum dots
  • X-ray reflectivity

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