A three-coordinate and quadruply bonded Mo-Mo complex

Yi Chou Tsai*, Yang Miin Lin, Jen-Shiang K. Yu, Jenn Kang Hwang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

38 Scopus citations

Abstract

Reaction of MoCl3(THF)3 with [Me2Si{NLi(Dipp)}2]2 (Dipp = 2,6-i-PrC6H3) afforded a triply bonded dimolybdenum complex 1,2-Mo2Cl2[Me2Si(NDipp)2]2 1, spanned by two Me2Si[N(Dipp)]2 ligands, thus resulting in a syn conformation. The air- and moisture-sensitive compound 1 was characterized by NMR spectroscopic, elemental, and single-crystal X-ray crystallographic analysis. Reduction of 1 by Na/Hg yielded the quadruply bonded dimeric complex Mo2[Me2Si(NDipp)2]2 2, which was also characterized by the aforementioned analytical methods. The Mo-Mo bond was determined to be 2.1784(12) Å, which is considered a long quadruple bond. In addition, density functional theory (DFT) computations on compound 2 provided insight into the intriguing Mo-Mo quadruple bond.

Original languageEnglish
Pages (from-to)13980-13981
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number43
DOIs
StatePublished - 1 Nov 2006

Fingerprint Dive into the research topics of 'A three-coordinate and quadruply bonded Mo-Mo complex'. Together they form a unique fingerprint.

Cite this