A quaternary germanium(II) phosphate, Na[Ge 4 (PO 4 ) 3 ]

Chi-Shen Lee*, Sheng Feng Weng

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

A new germanium(II) phosphate, sodium tetra-germanium tris-(phosphate), Na[Ge4(PO4)3], has been synthesized by a solid-state reaction. The compound is isotypic with A[Sn4(PO4)3] (A = Na, K, NH4). It features a [Ge4(PO4)3] - framework made up of GeO3 pyramids and PO4 tetra-hedra, which are linked by shared corners, yielding a three-dimensional structure. The crystal studied showed partial inversion twinning.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number3
DOIs
StatePublished - 10 Mar 2008

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