A Palladium/Light System Combined with Hanztsch Ester: Radical Vinylation of Alkyl Iodides with Vinyl Bromides

Shuhei Sumino, Ilhyong Ryu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

Radical vinylation of alkyl iodides with vinyl bromides proceeds smoothly with a combined Pd/light/Hanztsch ester system. In this reaction system, the Hanztsch ester acts as an effective reducing reagent of PdII to Pd0 that generates key alkyl radicals via single electron transfer (SET) with alkyl iodides upon photo-excitation.

Original languageEnglish
Pages (from-to)410-413
Number of pages4
JournalAsian Journal of Organic Chemistry
Volume6
Issue number4
DOIs
StatePublished - Apr 2017

Keywords

  • Hanztsch ester
  • palladium
  • photocatalysis
  • radical reactions
  • redox chemistry

Fingerprint Dive into the research topics of 'A Palladium/Light System Combined with Hanztsch Ester: Radical Vinylation of Alkyl Iodides with Vinyl Bromides'. Together they form a unique fingerprint.

Cite this