A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)6

Annamalai Senthilvelan, Gene Hsiang Lee, Wen-Sheng Chung*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The Mo(CO)6-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition.

Original languageEnglish
Pages (from-to)7179-7183
Number of pages5
JournalTetrahedron Letters
Volume47
Issue number40
DOIs
StatePublished - 2 Oct 2006

Keywords

  • Adamantane isoxazolines
  • Enaminoketones
  • Isomerization
  • Photorearrangement

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