A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)6

Annamalai Senthilvelan; Gene Hsiang Lee; Wen-Sheng Chung

doi:10.1016/j.tetlet.2006.07.156

A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)₆

Annamalai Senthilvelan, Gene Hsiang Lee, Wen-Sheng Chung^*

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The Mo(CO)₆-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition.

Original language	English
Pages (from-to)	7179-7183
Number of pages	5
Journal	Tetrahedron Letters
Volume	47
Issue number	40
DOIs	https://doi.org/10.1016/j.tetlet.2006.07.156
State	Published - 2 Oct 2006

Keywords

Adamantane isoxazolines
Enaminoketones
Isomerization
Photorearrangement

Access to Document

10.1016/j.tetlet.2006.07.156

Fingerprint Dive into the research topics of 'A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)<sub>6</sub>'. Together they form a unique fingerprint.

Cite this

@article{406a70a8bdc140bbb185eb0f0f07afaa,

title = "A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)6",

abstract = "The Mo(CO)6-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition.",

keywords = "Adamantane isoxazolines, Enaminoketones, Isomerization, Photorearrangement",

author = "Annamalai Senthilvelan and Lee, {Gene Hsiang} and Wen-Sheng Chung",

year = "2006",

month = oct,

day = "2",

doi = "10.1016/j.tetlet.2006.07.156",

language = "English",

volume = "47",

pages = "7179--7183",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "40",

}

TY - JOUR

T1 - A novel photoinduced ring opening and isomerization of adamantane-2-spiro isoxazolines using Mo(CO)6

AU - Senthilvelan, Annamalai

AU - Lee, Gene Hsiang

AU - Chung, Wen-Sheng

PY - 2006/10/2

Y1 - 2006/10/2

N2 - The Mo(CO)6-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition.

AB - The Mo(CO)6-mediated photoinduced ring-opening reactions of adamantane isoxazolines involve novel rearrangement that provide enaminoketones as major products and β-hydroxy ketones as minor ones; in contrast, only β-hydroxy ketones and α,β-unsaturated ketones were obtained under thermal condition.

KW - Adamantane isoxazolines

KW - Enaminoketones

KW - Isomerization

KW - Photorearrangement

UR - http://www.scopus.com/inward/record.url?scp=33747881855&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2006.07.156

DO - 10.1016/j.tetlet.2006.07.156

M3 - Article

AN - SCOPUS:33747881855

VL - 47

SP - 7179

EP - 7183

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 40

ER -