A nanoscale shape memory oxide

Jinxing Zhang*, Xiaoxing Ke, Gaoyang Gou, Jan Seidel, Bin Xiang, Pu Yu, Wen I. Liang, Andrew M. Minor, Ying-hao Chu, Gustaaf Van Tendeloo, Xiaobing Ren, Ramamoorthy Ramesh

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

74 Scopus citations


Stimulus-responsive shape-memory materials have attracted tremendous research interests recently, with much effort focused on improving their mechanical actuation. Driven by the needs of nanoelectromechanical devices, materials with large mechanical strain, particularly at nanoscale level, are therefore desired. Here we report on the discovery of a large shape-memory effect in bismuth ferrite at the nanoscale. A maximum strain of up to ∼14% and a large volumetric work density of ∼600±90Jcm-3 can be achieved in association with a martensitic-like phase transformation. With a single step, control of the phase transformation by thermal activation or electric field has been reversibly achieved without the assistance of external recovery stress. Although aspects such as hysteresis, microcracking and so on have to be taken into consideration for real devices, the large shape-memory effect in this oxide surpasses most alloys and, therefore, demonstrates itself as an extraordinary material for potential use in state-of-art nanosystems.

Original languageEnglish
Article number2768
Number of pages8
JournalNature Communications
StatePublished - 19 Nov 2013

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