1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion

Hsuch-Ju Liu; Julie Guihaumé; Thomas Davin; Christophe Raynaud; Odile Eisenstein; T. Don Tilley

doi:10.1021/ja507799e

1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion

Hsuch-Ju Liu, Julie Guihaumé, Thomas Davin, Christophe Raynaud, Odile Eisenstein^*, T. Don Tilley

^*Corresponding author for this work

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

An intramolecular 1,2(α)-H migration in a saturated ruthenium stannylene complex, to form a ruthenostannylene complex, involves a reversal of the role for a coordinated stannylene ligand, from that of an electron donor to an acceptor in the transition state. This change in the bonding properties for a stannylene group, with a simple molecular motion, lifts the usual requirement for generation of an unsaturated metal center in migration chemistry.

Original language	English
Pages (from-to)	13991-13994
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	40
DOIs	https://doi.org/10.1021/ja507799e
State	Published - 8 Oct 2014

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abstract = "An intramolecular 1,2(α)-H migration in a saturated ruthenium stannylene complex, to form a ruthenostannylene complex, involves a reversal of the role for a coordinated stannylene ligand, from that of an electron donor to an acceptor in the transition state. This change in the bonding properties for a stannylene group, with a simple molecular motion, lifts the usual requirement for generation of an unsaturated metal center in migration chemistry.",

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1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion. / Liu, Hsuch-Ju; Guihaumé, Julie; Davin, Thomas; Raynaud, Christophe; Eisenstein, Odile; Tilley, T. Don.

In: Journal of the American Chemical Society, Vol. 136, No. 40, 08.10.2014, p. 13991-13994.

Research output: Contribution to journal › Article › peer-review

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